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The active antioxidant compound within milk thistle is the flavonoid complex called Silymarin. This antioxidant is one of the most powerful liver detoxifying agents. It helps to boost glutathione and superoxide dismutase

Fate of dietary glutathione: disposition in the gastrointestinal tract Am J Physiol Gastrointest Liver Physiol

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For the scenario of "Maximum Wrinkle Reduction," research data suggests GHK-Cu may be more relevant

oxidized glutathione (GSH/GSSG) ratio serves as an indicator of oxidative stress